Di-n-butyl[4-hydroxy-N′-(3-methoxy-2-oxidobenzylidene-κO 2)benzohydrazidato-κ2 N,O]tin(IV)
نویسندگان
چکیده
In the title compound, [Sn(C4H9)2(C15H12N2O4)], the Sn(IV) atom is coordinated by the N, O and O' atoms from the tridentate Schiff base dianion in an overall cis-C2SnNO2 trigonal-bipyramidal geometry. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds, forming a chain running along [001].
منابع مشابه
Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2 O,N′}tin(IV)
The deprotonated Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(18)H(12)N(2)O(3))], O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C(2)NO(2)Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)°]. The hydr-oxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent mol-ecule, the hydrogen-bondin...
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متن کامل[N-(3-Methoxy-2-oxidobenzylidene-κO 2)alaninato-κ2 N,O]diphenyltin(IV)
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013